| Chef de misssion | Titre | Carrière | Nomination | Présentation des lettres de créance | Fin de l'affectation |
| Woodsworth, Charles James | H-C | C | 1968/09/06 | 1969/02/10 | 1969/07/04 |
| Carter, Harry Havilland | H-C | C | 1969/07/15 | 1970/04/01 | 1972/08/04 |
| Campbell, Arthur Grant | H-C | C | 1972/06/01 | 1973/02/08 | 1976/08/31 |
| Grande, George Kinnear | H-C | C | 1976/06/29 | 1976/11/23 | 1979/02/28 |
| Middleton, Robert Morrice | H-C | C | 1978/12/21 | 1979/06/26 | 1982/08/20 |
| Lee, Edward Graham | H-C | C | 1982/09/22 | 1983/01/12 | 1986/09/13 |
| MacLean, Ronald Stuart | H-C | C | 1987/03/19 | | |
| Westdal, Christopher William | H-C | C | 1992/02/13 | | |
| Brault, Marc | H-C | C | 1994/11/25 | 1994/03/10 | |
| Perron, Arthur C. | H-C | C | 1995/09/26 | 1996/03/21 | |
| Bartleman, James Karl | H-C | C | 1999/03/19 | | |
| Edwards, Lucie Geneviève | H-C | C | 2000/01/07 | 2000/03/16 | |
| Scrimshaw, Sandelle D. | H-C | C | 2004/05/19 | | |
| Archibald, Ruth | H-C | C | 2007/03/13 | | |
| Baker, Philip | H-C | C | 2010/05/05 | | |
| Latulippe, Alain | H-C | C | 2010/11/17 | | |
| Barber, Shawn | H-C | C | 2014/05/27 | 2014/10/09 | 2016/07 |
| Chevrier, Antoine | H-C | C | 2016/09/02 | | 2018/08 |
| Delany, Caroline | H-C | C | 2019/11/01 | 2020/12 | |
| Nicholls, Sara | H-C | C | 2022/09/15 | | |