| Chef de misssion | Titre | Carrière | Nomination | Présentation des lettres de créance | Fin de l'affectation |
| Baudouin, Daniel Georges Marc | AEP | C | 1969/02/18 | 1969/06/07 | 1971/07/15 |
| Déry, Jean-Marie Gaétan | AEP | C | 1971/08/25 | 1972/03/04 | 1974/07/22 |
| Schioler, John Pontoppidan | AEP | C | 1974/07/04 | 1975/01/21 | 1976/06/18 |
| Wood, William McKenzie | AEP | C | 1977/03/24 | 1978/01/26 | 1978/08/19 |
| Chrétien, Raymond A.J. | AEP | C | 1978/07/13 | 1978/12/07 | 1981/06/16 |
| Saint-Martin, Jean-Guy Joseph Bernard | AEP | C | 1981/07/16 | 1981/10/01 | |
| Hare, Ewan Nigel | AEP | C | 1984/11/22 | 1984/11/22 | 1987/09/03 |
| Cupples, Colleen Leora | AEP | C | 1987/09/10 | 1987/12/18 | |
| Laverdure, Claude | AEP | C | 1989/09/28 | 1989/11/03 | 1992/09/07 |
| Frenette, Réjean | AEP | C | 1992/10/30 | 1992/10/30 | |
| Edwards, Lucie Geneviève | AEP | C | 1994/11/25 | | 1995/08/03 |
| Dussault, Bernard | AEP | C | 1995/09/26 | 1995/11 | 1998/08/08 |
| Campbell, Gerald K. | AEP | C | 1999/03/19 | 1998/11/16 | 2002/07/12 |
| Wall, James | AEP | C | 2002/10/31 | 2003/04/03 | 2006/08/10 |
| Hynes, Ross | AEP | C | 2006/06/14 | 2006/10/26 | |
| Collins, David | AEP | C | 2010/11/17 | | |
| Angell, David | AEP | C | 2013/02/11 | | 2016/07 |
| Hradecky, Sara | AEP | C | 2016/09/21 | | 2018/10 |
| Stadelbauer, Lisa | AEP | C | 2018/11/01 | 2019/07/02 | 2021/04/30 |