| Chef de misssion | Titre | Carrière | Nomination | Présentation des lettres de créance | Fin de l'affectation |
| Charpentier, Fulgence | AEP | C | 1962/03/01 | 1962/12/06 | 1965/06/05 |
| Blouin, Georges-Henri | AEP | C | 1965/06/03 | 1965/09/24 | 1967/07/02 |
| Thibault, J.E. | AEP | C | 1967/09/28 | 1967/11/27 | 1969/09/23 |
| Rousseau, Charles Odilon Roger | AEP | C | 1970/04/14 | 1970/03/27 | 1972/06/05 |
| Asselin, Pierre Léon Gérard | AEP | C | 1972/04/22 | 1972/09/30 | 1974/11/24 |
| Châtillon, Claude Charles-Edouard | AEP | C | 1975/10/21 | 1976/01/13 | 1978/06/12 |
| Duguay, Gilles Horace J. | AEP | C | 1978/07/13 | 1979/02/07 | 1980/09/03 |
| Denault, Jacques D.E. | AEP | C | 1980/07/10 | | 1982/07/31 |
| Saint-Pierre, Claude Jean | AEP | C | 1982/09/22 | 1982/12/14 | |
| Faguy, Marc | AEP | C | 1984/08/31 | 1985/01/30 | 1987/09/05 |
| Simard, André S. | AEP | C | 1987/09/10 | 1987/12/16 | 1989/07/16 |
| Leahy, Anne | AEP | C | 1989/10/12 | 1990/03/20 | 1992/03/10 |
| Després, Arsène A. | AEP | C | 1992/08/27 | 1992/11/10 | |
| Giguère, Pierre | AEP | C | 1995/09/26 | 1996/11/06 | |
| Baillargeon, Claude | AEP | C | 1999/03/19 | | |
| Perrault, Michel | AEP | C | 2000/07/26 | | |
| Savaria, Jules | AEP | C | 2004/03/18 | | |
| Lavoie, Jean-Pierre | AEP | C | 2007/01/15 | | |
| Pelletier, Jean-Carol | AEP | C | 2010/03/10 | | |
| Charette, Laurent | AEP | C | 2012/06/06 | | |
| Rossetti, Dominique | AEP | C | 2013/02/11 | 2013/06/19 | |
| Bendaoud, Salah-Eddine | AEP | C | 2016/03/11 | | 2018/09/03 |
| Norfolk, Adrian | AEP | C | 2018/09/26 | | |
| O'Neil, Nathalie | AEP | C | 2019/04/25 | | 2019/07 |
| Bale, Richard | AEP | C | 2019/10/21 | 2020/02/12 | |
| Anderson, Lorraine | AEP | C | 2022/09/15 | | |