| Chef de misssion | Titre | Carrière | Nomination | Présentation des lettres de créance | Fin de l'affectation |
| Williams, Bruce MacGillivray | AEP | C | 1962/04/18 | | 1962/07/01 |
| Cornett, Donald Macalister | AEP | C | 1962/11/29 | 1963/09/26 | 1965/01/07 |
| McGaughey, Charles Eustace | AEP | C | 1965/03/30 | | |
| Hart, Albert Frederick | AEP | C | 1966/08/03 | 1967/02/24 | 1968/09/13 |
| Hicks, Douglas Barcham | AEP | C | 1968/10/24 | 1969/01/24 | 1970/03/11 |
| Charpentier, Wilfrid Joseph Georges | AEP | C | 1969/12/17 | 1970/03/11 | |
| Mathieu, Gilles | AEP | C | 1972/06/29 | 1972/09/11 | |
| de Goumois, Michel | AEP | C | 1975/08/06 | 1975/11/06 | 1977/12 |
| Lalande, Joseph Ernest Gilles | AEP | NC | 1978/03/23 | 1978/05/08 | |
| Hébert, Ernest | AEP | C | 1980/07/10 | 1980/11/29 | |
| Bell, John Peter | AEP | C | 1982/12/22 | 1984/02/23 | 1987/04 |
| Saint-Martin, Jean-Guy Joseph Bernard | AEP | C | 1987/07/20 | 1988/02/02 | |
| Bélisle, J. Denis | AEP | C | 1991/08/13 | | 1994/06/12 |
| Laporte, Suzanne | AEP | C | 1994/07/15 | 1994/09/09 | |
| McMaster, Donald | AEP | C | 1998/07/15 | 1999/01/06 | |
| Gauvreau, Émile | AEP | C | 2001/07/16 | 2001/10/04 | |
| Lévesque, Michèle | AEP | C | 2003/07/31 | | |
| Massip, Marie-Isabelle | AEP | C | 2006/07/13 | 2006/09/21 | |
| de Varennes, Chantal | AEP | C | 2011/09/21 | 2011/11/09 | 2015/07 |
| McCullagh, Patricia | AEP | C | 2015/07/20 | 2015/10/06 | 2017 |
| Shouldice, Julie | AEP | C | 2017/08/17 | 2017/09/29 | 2020/08 |
| Demers, Claude | AEP | C | 2020/10/09 | 2021/05/07 | 2022/02/02 |
| Blanc, Anderson | AEP | C | 2022/07/29 | 2022/09/09 | |