| Chef de misssion | Titre | Carrière | Nomination | Présentation des lettres de créance | Fin de l'affectation |
| Meagher, Blanche Margaret | H-C | C | 1961/04/20 | 1961/08/14 | 1961/12/01 |
| Andrew, Arthur Julian | H-C | C | 1962/05/28 | 1962/08/27 | 1965/07/10 |
| Wainman-Wood, Thomas Blake Burrill | H-C | C | 1965/06/14 | 1965/08/04 | 1968/11/09 |
| Brown, John Clemence Gordon | H-C | C | 1968/10/31 | 1968/12/20 | 1970/01/18 |
| McGaughey, Charles Eustace | H-C | C | 1970/01/23 | 1970/05/19 | 1972/06/30 |
| Malone, Thomas Paul | H-C | C | 1972/05/23 | | 1975/09/02 |
| Lee, Edward Graham | H-C | C | 1975/07/29 | 1975/10/17 | 1979/07/03 |
| Stanford, Joseph Stephen | H-C | C | 1979/04/04 | 1979/10/16 | 1982/09/13 |
| Turner, Vernon George | H-C | C | 1982/09/22 | 1982/11/16 | |
| Bartleman, James Karl | H-C | C | 1986/01/10 | 1986/03/04 | 1990/11/01 |
| Bell, Michael Dougall | H-C | C | 1991/02/14 | 1991/04/15 | 1992/01/21 |
| Spector, Norman | H-C | C | 1992 | | |
| Berger, David | H-C | NC | 1995 | | |
| Bugailiskis, Alexandra | H-C | C | 1998/03/12 | 1998/04/30 | 2000/08/04 |
| Pillarella, Franco D. | H-C | C | 2000/07/26 | 2000/12/12 | |
| Moszczenska, Marta | H-C | C | 2006/06/14 | | |
| Beaulne, Philippe | H-C | C | 2009/06/09 | | 2013/07/30 |
| Wielgosz, Renata | H-C | C | 2009/09/30 | | |
| Peck, Robert | H-C | C | 2011/07/19 | 2012/01/10 | |
| Morrill, Keith | H-C | C | 2015/06/22 | 2016/02/29 | 2018/07 |
| Allen, Mark | H-C | C | 2018/12/14 | 2019/05/07 | |
| Asselin, Anna-Karine | H-C | C | 2022/11/04 | | |