| Chef de misssion | Titre | Carrière | Nomination | Présentation des lettres de créance | Fin de l'affectation |
| Berlis, Norman Frederick Henderson | H-C | C | 1964/04/09 | 1964/05/05 | 1965/07/27 |
| McGill, Allan Sydney | H-C | C | 1965/08/07 | 1965/10/22 | 1967/07 |
| Meagher, Blanche Margaret | H-C | C | 1967/02/09 | 1969/08/01 | |
| Cook, James Murray | H-C | C | 1969/07/15 | 1969/09/26 | 1972/07/22 |
| Olivier, William George Marcel | H-C | C | 1972/06/08 | | 1975/06/12 |
| Rau, Gerald Anthony | H-C | C | 1975/07/17 | | 1978/08/01 |
| Bruce, Geoffrey Franklin | H-C | C | 1978/06/08 | 1978/11/03 | 1982/02/25 |
| Miller, David Miles | H-C | C | 1982/05/06 | 1982/05/11 | |
| Andreychuk, A. Raynell | H-C | NC | 1987/02/05 | 1987/07/16 | 1990/10/29 |
| Smith, Lawrence Austin Hayne | H-C | C | 1990/09/12 | 1992/03 | 1993/01/30 |
| Edwards, Lucie Geneviève | H-C | C | 1992/08/27 | 1993/02/09 | 1995/08/03 |
| Dussault, Bernard | H-C | C | 1995/07/04 | 1995/08/21 | 1998/08/08 |
| Campbell, Gerald K. | H-C | C | 1998/07/15 | 1998/09/02 | 2002/07/12 |
| Wall, James | H-C | C | 2002/07/02 | 2002/10/22 | 2006/08/10 |
| Hynes, Ross | H-C | C | 2006/06/14 | 2006/10/11 | |
| Collins, David | H-C | C | 2010/08/31 | 2010/09/15 | |
| Angell, David | H-C | C | 2012/08/15 | 2012/12/18 | 2016/07 |
| Hradecky, Sara | H-C | C | 2016/08/10 | 2016/09/07 | 2018/10 |
| Stadelbauer, Lisa | H-C | C | 2018/09/04 | 2018/12/05 | 2021/04/30 |
| Thornley, Christopher | H-C | C | 2021/12/20 | 2022/04/01 | |