| Chef de misssion | Titre | Carrière | Nomination | Présentation des lettres de créance | Fin de l'affectation |
| Côté, Joseph Jean Martial | AEP | C | 1966/05/11 | 1969/07/04 | 1969/07/12 |
| Riddell, Gordon George | AEP | C | 1969/06/06 | | 1972/06/07 |
| Grenier, Raoul Jean | AEP | C | 1972/06/29 | | 1974/09/05 |
| Couvrette, Joseph Gilles André | AEP | C | 1974/06/10 | | 1976/06/16 |
| de Goumois, Michel | AEP | C | 1975/08/09 | 1976/01/16 | 1977/12/20 |
| Lalande, Joseph Ernest Gilles | AEP | NC | 1978/03/23 | 1978/09/01 | 1980/06/13 |
| Hébert, Ernest | AEP | C | 1980/07/10 | 1981/01/09 | |
| Bell, John Peter | AEP | C | 1982/12/22 | 1984/03/16 | |
| Saint-Martin, Jean-Guy Joseph Bernard | AEP | C | 1988/01/14 | 1987/12/01 | |
| Bélisle, J. Denis | AEP | C | 1992/02/13 | 1991/10/25 | 1994/06/12 |
| Laporte, Suzanne | AEP | C | 1994/07/15 | 1994/09/20 | |
| McCoy, Susan | AEP | C | 1995/07/04 | 1995/08/23 | |
| Boulanger, Yves | AEP | C | 1997/09/22 | 1997/09/26 | |
| Ouimet, Louise | AEP | C | 2001/07/16 | | |
| Roy, Isabelle | AEP | C | 2005/08/02 | 2005/09/02 | 2008/08 |
| Saint-Louis, Virginie | AEP | C | 2008/12/31 | | |
| de Lorimier, Louis | AEP | C | 2012/08/20 | | 2015/08 |
| Fredette, Marc-André | AEP | C | 2015/07/31 | 2015/09/18 | 2017/08/14 |
| Verret, Louis | AEP | C | 2017/08/17 | 2017/10/06 | 2019/08/31 |
| Elliott, Michael | AEP | C | 2019/08/26 | 2020/01/21 | |
| Lafrenière, François | AEP | C | 2022/10/07 | 2022/11/15 | |