| Chef de misssion | Titre | Carrière | Nomination | Présentation des lettres de créance | Fin de l'affectation |
| McGaughey, Charles Eustace | AEP | C | 1961/12/15 | 1962/03/02 | 1965/05/05 |
| Butler, Bertram Charles | AEP | C | 1965/03/25 | 1965/11/30 | 1967/08/11 |
| Britton, James Clelland | AEP | C | 1967/06/30 | 1967/11/19 | 1969/09/24 |
| Cox, Gordon Edwin | AEP | C | 1969/06/06 | 1969/10/22 | 1972/08/25 |
| Riddell, Gordon George | AEP | C | 1972/06/08 | 1972/10/09 | 1974/06/16 |
| Hearn, Godfrey Lewis | AEP | C | 1974/09/24 | 1974/09/26 | 1975/03/17 |
| Bauer, William Edward | AEP | C | 1975/07/17 | 1975/10/10 | 1979/06/04 |
| Bild, M. Fred | AEP | C | 1979/04/04 | 1979/08/24 | 1983/08/13 |
| Paynter, John Lawrence | AEP | C | 1983/10/13 | 1983/10/11 | 1987/08/15 |
| Smith, Lawrence Austin Hayne | AEP | C | 1987/11/26 | 1988/01/14 | |
| Perron, Arthur C. | AEP | C | 1990/11/08 | 1990/11/29 | 1994/07/12 |
| von Nostitz, Manfred Gustav | AEP | C | 1994/08/16 | 1994/09/08 | 1997/06/23 |
| Giroux, Bernard | AEP | C | 1997/07/10 | | |
| McAlister, Andrew | AEP | C | 2001/08/20 | 2001/10/17 | |
| Comeau, Denis | AEP | C | 2004/08/09 | 2004/10/12 | 2007/07/10 |
| Sproule, David | AEP | C | 2007/07/31 | 2007/12 | 2009/07 |
| Hoffmann, Ron | AEP | C | 2009/06/09 | | |
| Calvert, Philip | AEP | C | 2012/10/11 | 2013/12/12 | 2016/08 |
| Pottie, Donica | AEP | C | 2016/07/18 | 2016/09/26 | 2019/10 |
| Taylor, Sarah | AEP | C | 2019/11/19 | 2020/06/15 | 2023/09/11 |
