| Chef de misssion | Titre | Carrière | Nomination | Présentation des lettres de créance | Fin de l'affectation |
| Feaver, Herbert Frederick Brooks-Hill | AEP | C | 1961/02/08 | 1961/03/01 | 1964/06/30 |
| Garneau, René | AEP | C | 1964/04/20 | 1964/09/28 | 1968/05/04 |
| Pick, Alfred John | AEP | C | 1966/06/09 | 1966/09/29 | 1969/04/25 |
| Fortier, D'Iberville | AEP | C | 1969/07/31 | 1969/11/26 | 1972/08/11 |
| Gaudefroy, Henri | AEP | C | 1972/06/29 | 1972/09/02 | 1974/06/17 |
| Gignac, Jacques Gilles Bruno | AEP | C | 1974/06/10 | 1974/09/11 | 1977/08/04 |
| Touchette, Jean-Marcel | AEP | C | 1977/08/31 | 1977/10/13 | 1980/07/15 |
| Blanchette, Arthur Edward | AEP | C | 1980/07/10 | 1980/10/16 | 1983/08/23 |
| Weynerowski, Witold Maciej | AEP | C | 1983/10/13 | 1983/10/25 | 1986/08/09 |
| Williams, Timothy Angus | AEP | C | 1986/07/23 | 1986/11/08 | 1989/07/30 |
| Bujold, Marius Jean | AEP | C | 1989/08/24 | 1989/10/05 | 1993/08/12 |
| Roy, Michel | AEP | C | 1993/09/30 | 1993/09/30 | 1996/08/29 |
| Després, Arsène A. | AEP | C | 1996/06/03 | 1996/10/22 | |
| Simard, Jacques T. | AEP | C | 1999/08/11 | 2000/01/13 | 2004/03/01 |
| Licari, Wilfrid-Guy | AEP | C | 2004/01/22 | 2004/05/20 | 2006/02/22 |
| Picard, Bruno | AEP | C | 2006/06/14 | 2007/01/18 | 2009/08/23 |
| Delouya, Ariel | AEP | C | 2009/08/10 | 2009/11/19 | |
| Beaulieu, Sébastien | AEP | C | 2012/08/27 | 2012/09/21 | 2015/07 |
| McQueen, Carol | AEP | C | 2015/08/27 | 2015/12/03 | 2019/08 |
| Cousineau, Patrice | AEP | C | 2019/08/28 | 2019/10/24 | |
| Diguer, Lorraine | AEP | C | 2022/09/15 | 2022/11/11 | |