| Chef de misssion | Titre | Carrière | Nomination | Présentation des lettres de créance | Fin de l'affectation |
| Williams, Bruce MacGillivray | AEP | C | 1962/04/12 | | 1962/07/01 |
| Cornett, Donald Macalister | AEP | C | 1962/11/29 | 1963/07/27 | 1965/01/07 |
| McGaughey, Charles Eustace | AEP | C | 1965/03/30 | 1965/07/16 | 1966/06/09 |
| Hart, Albert Frederick | AEP | C | 1966/05/11 | | |
| Côté, Joseph Jean Martial | AEP | C | 1967/01/12 | 1967/06/08 | 1969/07/12 |
| Riddell, Gordon George | AEP | C | 1969/06/06 | | |
| Grenier, Raoul Jean | AEP | C | 1972/04/22 | | |
| Couvrette, Joseph Gilles André | AEP | C | 1974/06/10 | 1976/03/26 | |
| Asselin, Jacques J.A. | AEP | C | 1977/07/14 | 1977/09/00 | 1980/09/11 |
| Perron, Marc | AEP | C | 1980/07/10 | 1980/10/30 | |
| Cadieux, Michel | Chargé d'affaires a.i. | C | 1982/09/18 | | 1985/07/18 |
| Bujold, Marius Jean | AEP | C | 1982/09/22 | 1982/10/15 | |
| Dubois, Andrée | Chargé d'affaires a.i. | C | 1985/09/03 | | 1987/09/00 |
| April, Serge | AEP | C | 1985/11/21 | 1985/11/06 | |
| Nadeau, Jean | Chargé d'affaires a.i. | C | 1988/01/00 | | 1988/09/05 |
| Hubert, Jean-Paul | AEP | C | 1988/08/11 | | 1990/07/11 |
| Collin, Paul-André | Chargé d'affaires a.i. | C | 1989/01/15 | | |
| Bilodeau, Jacques | AEP | C | 1990/10/18 | 1990/10/19 | |
| Licari, Wilfrid-Guy | AEP | C | 1994/11/25 | 1995/02/03 | |
| Briand, Denis | AEP | C | 1995/08/18 | 1995/10/06 | |
| Beaulne, Philippe | AEP | C | 2001/07/16 | | |
| Marchand, Louise R. | AEP | C | 2006/08/25 | | |
| Bolduc, Jean-Pierre | AEP | C | 2007/10/11 | | |
| Calderwood, Perry | AEP | C | 2010/12/21 | 2012/02/22 | |
| Beaulne, Philippe | AEP | C | 2013/09/17 | | 2016/07 |
| Filiatrault, Lise | AEP | C | 2016/10/07 | | 2019/08/30 |
| Beaulieu, Sébastien | AEP | C | 2020/02/06 | 2020/09/25 | 2021/06/19 |
| Mounier, Marie-Geneviève | AEP | C | 2022/10/19 | | |